酸雨对桂林枯水期岩溶地下水δ13C_DIC及碳汇效应的影响   总被引：1，自引：0，他引：1       下载免费PDF全文

黄奇波  覃小群  刘朋雨  唐萍萍 《地球科学》2015,40(7):1237-1247

定量评价硫酸对岩溶碳汇效应的影响有助于提高岩石风化碳汇通量估算精度, 对当前全球气候变化研究意义重大.选取受酸雨影响的桂林岩溶区为研究对象, 在枯水期对研究区14个岩溶大泉和15条地下河水化学成分和碳同位素进行了测试分析, 结果表明: 岩溶大泉和地下河中阳离子以Mg2+和Ca2+为主, 阴离子以HCO₃-为主, 分别占阳离子和阴离子组成的90%以上, SO₄2-含量较低, 其含量范围为0.004~0.213mmol/L; 所占阴离子组成比例为0.12%~6.11%;δ13C_DIC、[Ca2++Mg2+]/[HCO₃-]更偏向于碳酸溶解端元, 离硫酸溶解端元距离远, 证实硫酸参与碳酸盐岩的溶解对地下水无机碳(dissolved inorganic carbon, 简称DIC)及δ13C_DIC的影响有限; 与Sr2+/Ca2+值一样, δ13C_DIC主要受径流条件控制, 其大小可以反映地下水径流条件的强弱.利用化学计量关系计算出由硫酸溶蚀碳酸盐岩的平均比例为22.64%, 产生的DIC(HCO₃-_H2SO4)占总DIC的平均比例为13.04%, 碳酸产生的DIC(HCO₃-_H2CO3)占地下水总DIC的比例为86.96%, 其中来源于土壤大气中的HCO₃-比例为43.48%.因此, 扣除硫酸对地下水中DIC的贡献后, 岩溶碳汇效应将减少13.04%.   相似文献   

气候变暖对湖泊热力及溶解氧分层影响研究进展   总被引：4，自引：0，他引：4       下载免费PDF全文

张运林 《水科学进展》2015,26(1):130-139

气候变暖对湖泊物理、化学、生物和生态系统有着复杂而深刻的直接和间接影响,而具体影响随研究区域和水体表现不尽相同。气候变暖通过改变湖泊热力和溶解氧分层进而影响湖泊生物过程和生态系统结构与功能。从全球湖泊变暖趋势、长期缓慢气温上升、极端高温事件以及气候情景模拟等方面详细综述了气候变暖对湖泊热力及溶解氧分层影响的研究进展。研究表明,全球不同区域湖泊均存在不同程度的变暖趋势;长期缓慢气温上升和短期极端高温均会造成湖泊热力分层提前,分层结束推迟,分层时间延长,混合层和温跃层深度下降,以及热稳定性增加;相伴随的是溶解氧扩散深度和氧跃层深度明显下降,加剧了湖泊底部好氧和厌氧环境。除了这种直接影响外,气候变暖引起的流域降水、入湖物质的变化以及风速的变化也会对湖泊热力和溶解氧分层产生许多间接的影响,因此未来仍然需要更多的实验证据、经验和数值模型来验证和预测气候变暖对湖泊热力及溶解氧分层的影响。  相似文献   

威海市褚岛北部海域CDOM和COD分布特征遥感分析     

黄妙芬  王忠林  邢旭峰  陈亮  孙忠泳 《海洋技术学报》2018,(2):63-70

根据2017年7月和9月在山东威海褚岛北部海域现场测量的COD_(Mn)(Chemical oxygen demand)值和水体表观光学量,结合COMS(Communication,OceanMeteorological Satellite)上搭载的传感器GOCI(Geostationary Ocean Color Imager)所提供的有色可溶性有机物(Chromophoric dissolved organic matter,CDOM)产品,利用星地同步观测数据对现有的基于遥感反射比反演CDOM的模式进行验证,确定适合该海域的CDOM浓度遥感反演模式;通过对测试海域化学需氧量与遥感反演的水体CDOM浓度相关性分析,建立利用CDOM反演COD_(Mn)的遥感模式,并将该模式应用于测试海域LANDSAT 8/OLI(Operational Land Imager)遥感图像上,获取该海域COD_(Mn)浓度专题图,基于这些专题图分析了测试海域COD_(Mn)时空分布特征。结果表明:(1)基于GOCI产品的CDOM浓度值随时间和站点动态变化大,离岸越近数值越高,同一地点水体前后相差近1 h的数值变化也较大;(2)基于LANDSAT 8/OLI遥感数据反演的COD_(Mn)浓度时间动态变化大,总体来看褚岛附近水体的COD_(Mn)含量相对较低,褚岛以北海域水体COD_(Mn)含量有所增加,褚岛西侧水体的COD_(Mn)含量较东侧水体COD_(Mn)含量来说整体偏高。  相似文献   

Suspended sediment and total dissolved solid yield patterns at the headwaters of Urumqi River,northwestern China: a comparison between glacial and non‐glacial catchments          下载免费PDF全文

Wenhua Gao  Shu Gao  Zhongqin Li  X. X. Lu  Mingjun Zhang  Shengjie Wang 《水文研究》2014,28(19):5034-5047

In order to understand the differences in the suspended sediment and total dissolved solid (TDS) yield patterns between the glacial and non‐glacial catchments at the headwaters of Urumqi River, northwestern China, water samples were collected from a glacier catchment and an empty cirque catchment within the region, during three melting seasons from 2006 to 2008. These samples were analyzed to estimate suspended sediment and TDS concentrations, fluxes and erosion rates in the two adjoining catchments. There were remarked differences in suspended sediment and TDS yield patterns between the two catchments. Suspended sediment concentrations were controlled mainly by the sediment source, whereas TDS concentrations were primarily related to the hydrologic interaction with soil minerals. Generally, the glacial catchment had much higher suspended sediment and TDS yields, together with higher denudation rates, than the non‐glacial catchment. Overall, glacial catchment was mainly dominated by physical denudation process, whereas the non‐glacial catchment was jointly influenced by physical and chemical denudation processes. The observed differences in material delivery patterns were mainly controlled by the runoff source and the glacial processes. The melting periods of glacier and snow were typically the most important time for the suspended sediment and TDS yields. Meanwhile, episodic precipitation events could generate disproportionately large yields. Subglacial hydrology dynamics, glaciers pluck and grind processes could affect erodibility, and the large quantities of dust stored on the glacier surface provided additional sources for suspended sediment transport in the glacial catchment. These mechanisms imply that, in response to climate change, the catchment behaviour will be modified significantly in this region, in terms of material flux. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

基于神经网络模型的湛江湾水体有色溶解有机物的遥感估算     

余果  付东洋  刘大召  刘贝  廖珊  王立安  张小龙 《海洋科学》2018,42(9):73-80

有色溶解有机物(Colored Dissolved Organic Matter, CDOM)是水体中重要的水质参数之一,是水色遥感的重要研究对象,如何构建适合特定区域的近海二类水体CDOM反演模型一直是国内外研究难点。本文利用2017年5月26～29日对南海西北部海域湛江湾20个站位采集的水样和测量的光谱资料,分析归一化遥感反射率与CDOM浓度a_g(400)的相关性,发现最大负相关系数出现在586nm处,选择580、585、590、595nm这四个波段处的归一化遥感反射率与a_g(400)建立了多元线性回归模型、BP(Back-Propagation)神经网络模型和RBF(Radial-Basis Function)神经网络模型,并与其他算法模型进行对比分析。结果发现, BP和RBF神经网络模型的平均相对误差和均方根误差均远小于多元线性回归模型和其他算法模型,神经网络模型的预测值与实测值拟合效果要优于多元线性回归模型。研究表明,神经网络模型更适合于湛江湾有色溶解有机物的遥感估算。  相似文献   

Dissolved inorganic carbon evolution in neutral discharge from mine tailings piles          下载免费PDF全文

Hendratta N. Ali  Eliot A. Atekwana 《水文研究》2016,30(13):2079-2091

We measured the concentrations of dissolved inorganic carbon (DIC) and major ions and the stable carbon isotope ratios of DIC (δ¹³C_DIC) in two creeks discharging from carbonate‐rich sulphide‐containing mine tailings piles. Our aim was to assess downstream carbon evolution of the tailings discharge as it interacted with the atmosphere. The discharge had pH of 6.5–8.1 and was saturated with respect to carbonates. Over the reach of one creek, the DIC concentrations decreased by 1.1 mmol C/l and δ¹³C_DIC increased by ~4.0‰ 200 m from the seep source. The decrease in the DIC concentrations was concomitant with decreases in the partial pressure of CO_2(aq) because of the loss of excess CO_2(aq) from the discharge. The corresponding enrichment in the δ¹³C_DIC is because of kinetic isotope fractionation accompanying the loss of CO_2(g). Over the reach of the other creek, there was no significant decrease in the DIC concentrations or notable changes in the δ¹³C_DIC. The insignificant change in the DIC concentrations and the δ¹³C_DIC is because the first water sample was collected 160 m away from the discharge seep, not accessible during this research. In this case, most of the excess CO_2(aq) was lost before our first sampling station. Our results indicate that neutral discharges from tailings piles quickly lose excess CO_2(aq) to the atmosphere and the DIC becomes enrich in ¹³C. We suggest that a significant amount of carbon cycling in neutral discharges from tailings piles occur close to the locations where the discharge seeps to the surface. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

A long‐term study of stable isotopes as tracers of processes governing water flow and quality in a lowland river basin: the upper Thames,UK          下载免费PDF全文

W. George Darling  Michael J. Bowes 《水文研究》2016,30(13):2178-2195

A long‐term study of O, H and C stable isotopes has been undertaken on river waters across the 7000‐km² upper Thames lowland river basin in the southern UK. During the period, flow conditions ranged from drought to flood. A 10‐year monthly record (2003–2012) of the main River Thames showed a maximum variation of 3‰ (δ¹⁸O) and 20‰ (δ²H), although interannual average values varied little around a mean of –6.5‰ (δ¹⁸O) and –44‰ (δ²H). A δ²H/δ¹⁸O slope of 5.3 suggested a degree of evaporative enrichment, consistent with derivation from local rainfall with a weighted mean of –7.2‰ (δ¹⁸O) and –48‰ (δ²H) for the period. A tendency towards isotopic depletion of the river with increasing flow rate was noted, but at very high flows (>100 m³/s), a reversion to the mean was interpreted as the displacement of bank storage by rising groundwater levels (corroborated by measurements of specific electrical conductivity). A shorter quarterly study (October 2011–April 2013) of isotope variations in 15 tributaries with varying geology revealed different responses to evaporation, with a well‐correlated inverse relationship between Δ¹⁸O and baseflow index for most of the rivers. A comparison with aquifer waters in the basin showed that even at low flow, rivers rarely consist solely of isotopically unmodified groundwater. Long‐term monitoring (2003–2007) of carbon stable isotopes in dissolved inorganic carbon (DIC) in the Thames revealed a complex interplay between respiration, photosynthesis and evasion, but with a mean interannual δ¹³C‐DIC value of –14.8 ± 0.5‰, exchange with atmospheric carbon could be ruled out. Quarterly monitoring of the tributaries (October 2011–April 2013) indicated that in addition to the aforementioned factors, river flow variations and catchment characteristics were likely to affect δ¹³C‐DIC. Comparison with basin groundwaters of different alkalinity and δ¹³C‐DIC values showed that the origin of river baseflow is usually obscured. The findings show that long‐term monitoring of environmental tracers can help to improve the understanding of how lowland river catchments function. Copyright © NERC 2015. Hydrological Processes © 2015 John Wiley & Sons, Ltd.  相似文献   

Mercury and methylmercury biogeochemistry in a thawing permafrost wetland complex,Northwest Territories,Canada          下载免费PDF全文

J. Gordon  W. Quinton  B. A. Branfireun  D. Olefeldt 《水文研究》2016,30(20):3627-3638

In arctic and sub‐arctic environments, mercury (Hg), more specifically toxic methylmercury (MeHg), is of growing concern to local communities because of its accumulation in fish. In these regions, there is particular interest in the potential mobilization of atmospherically deposited Hg sequestered in permafrost that is thawing at unprecedented rates. Permafrost thaw and the resulting ground surface subsidence transforms forested peat plateaus into treeless and permafrost‐free thermokarst wetlands where inorganic Hg released from the thawed permafrost and draining from the surrounding peat plateaus may be transformed to MeHg. This study begins to characterize the spatial distribution of MeHg in a peat plateau–thermokarst wetland complex, a feature that prevails throughout the wetland‐dominated southern margin of thawing discontinuous permafrost in Canada's Northwest Territories. We measured pore water total Hg, MeHg, dissolved organic matter characteristics and general water chemistry parameters to evaluate the role of permafrost thaw on the pattern of water chemistry. A gradient in vegetation composition, water chemistry and dissolved organic matter characteristics followed a toposequence from the ombrotrophic bogs near the crest of the complex to poor fens at its downslope margins. We found that pore waters in poor fens contained elevated levels of MeHg, and the water draining from these features had dissolved MeHg concentrations 4.5 to 14.5 times higher than the water draining from the bogs. It was determined through analysis of historical aerial images that the poor fens in the toposequence had formed relatively recently (early 1970s) as a result of permafrost thaw. Differences between the fens and bogs are likely to be a result of their differences in groundwater function, and this suggests that permafrost thaw in this landscape can result in hotspots for Hg methylation that are hydrologically connected to downstream ecosystems. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

川西高原地区岩石中硒的地球化学特征和影响因素   总被引：1，自引：0，他引：1  

杨妍萍  刘晓端  刘久臣  汤奇峰  孟拓  朱晓华 《岩矿测试》2020,39(1):115-126

川西高原土壤、水体等多种介质研究表明,该地区的硒含量偏低,天然土壤剖面硒为0.06～0.16μg/g,表层土壤中硒含量为0.075～0.204μg/g,沉积物中硒含量为0.069～0.310μg/g,地表水中硒含量为nd～0.096μg/L,地下水中硒含量为nd～0.058μg/L,均低于我国相应环境介质中硒的平均含量,影响到当地人体健康。本文采集川西高原地区80件岩石样品,同时采集6套岩心样品,这些样品主要以板岩、砂岩、灰岩和页岩为主。采用原子荧光光谱法(AFS)测定硒含量,研究川西高原阿坝地区岩石与岩心样品中硒的地球化学特征和低硒的影响因素。结果表明:岩石硒含量范围为0.030～0.282μg/g,平均值0.09μg/g,低于硒土壤背景值。不同类型岩石中的硒含量大小为:页岩灰岩板岩砂岩。岩石中硒含量在不同地区也表现出较大的差异:松潘阿坝壤塘马尔康九寨沟若尔盖红原,可能是受到岩石类型及有机质和地质环境的影响所致。岩心各剖面的硒含量最小值为0.02～0.07μg/g,最大值为0.21～0.34μg/g,平均值为0.06～0.17μg/g,各钻孔的硒含量明显低于硒的地壳丰度。本研究认为,硒的分布受地质环境、有机质、岩石致密性等条件限制,低硒的地质环境是导致岩石中的硒含量较低的最主要因素。  相似文献   

刘公岛海洋牧场底层海水溶解氧浓度的变化特征     

李兆钦  李欣  孙利元  刘子洲  顾艳镇  翟方国  李培良 《海洋与湖沼》2019,50(1):86-99

由于缺乏长期观测资料,前人对山东半岛邻近海域海水溶解氧的时间变化和空间分布特征的研究较少。本文基于威海刘公岛海洋牧场于2016年7月20日至2017年3月14日期间,利用生态环境实时在线观测系统获得的底层海水的温度、盐度、水深、溶解氧数据,分析了该牧场海水溶解氧浓度的时间变化特征及其影响因素,并探讨了低氧灾害发生的可能性。结果表明在观测期间,该牧场海水溶解氧浓度以季节变化为主,冬季最大、夏季最小,其中2月份平均值最高,约为10.86mg/L,8月份平均值最低,约为5.91mg/L。同时海水溶解氧浓度也存在显著的小时变化和日变化,且变化幅度于8月份最大、3月份最小。影响海水溶解氧浓度变化的主要因素是海水温度,溶解氧浓度随着温度的季节性变化而变化。夏季,水体分层会使溶解氧浓度发生大幅度的降低,大风过程对于溶解氧浓度也有一定的影响,通过打破夏季的季节性温跃层使水体发生垂向混合从而为海底提供氧气,但大风过程之后的几天会出现溶解氧浓度降低的现象。本次研究发现刘公岛海洋牧场在观测期间不存在低氧现象。  相似文献